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Stable Isotope Geochemistry

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Subject:
Re: enriched water for tracer study
From:
Stephen Romaniello <[log in to unmask]>
Reply To:
Stable Isotope Geochemistry <[log in to unmask]>
Date:
Thu, 20 Aug 2009 07:46:25 -0700
Content-Type:
text/plain
Parts/Attachments:
text/plain (73 lines)
It might be easier to use an inert tracer like sulfur hexafluoride.
SF6 has been successfully used in the oceanography community to track
mixing of water masses many times now. Assuming a 3000 gallon
injection, and a price of about $4/mole for SF6, you could spike your
entire experiment to 500 uM for about $25 worth of tracer.

Also, for those of you teaching students, this is a fun and
attention-getting classroom exercise that uses SF6 to display aspects
of buoyancy, density, and isostasy:

http://sciencehack.com/videos/view/mb3ktPn1MQk

-Steve

------------------------------
Stephen Romaniello
Ph.D. Student
Science Foundation of Arizona Graduate Fellow
School of Earth & Space Exploration
Arizona State University
Tempe, AZ  85287
m. 860-462-6906



On Wed, Aug 19, 2009 at 8:19 PM, Howard Spero<[log in to unmask]> wrote:
> How much of an offset do you need from the original aquifer?  Could you use
> glacial ice and inject water with delta D of -350 or -400 per mil (-35 to
> -40 d18O)?
> Howie
>
>
>
> Please note that as of July 1, 2009,
> Howie's email address will permanently change to:
>  [log in to unmask]
> ***********************************************
> Prof. Howard Spero
> Department of Geology
> University of California Davis
> Davis CA 95616
>  https://www.geology.ucdavis.edu/faculty/spero.html
> (530)752-3307
> [log in to unmask]
> UC Davis Stable Isotope Laboratory:
> http://stable-isotopes.geology.ucdavis.edu/
> ***********************************************
> On Aug 19, 2009, at 7:10 PM, Devon Rowe wrote:
>
> We are contemplating injecting potassium permanganate to study effects on
> contaminants in a shallow groundwater aquifer – in recent discussion with a
> colleague of mine, the idea of mixing our permanganate salt with
> isotopically labeled water was brought up, to be able to track the migration
> through a fractured bedrock system after the permanganate is consumed.
> Where/how does one obtain large quantities of labeled water – we need to
> inject several thousand gallons.  Does anyone experience with such an
> exercise, or suggestions?  I recall the recent discussion about how to make
> your own enriched waters in a lab setting via evaporation, but the
> quantities were much less than we need (and we don’t have access to a lab).
>
> Any suggestions welcome,
> Devon
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