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Stable Isotope Geochemistry

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Subject:
Source Stretching, CO-H2O fractionation
From:
Dyke Andreasen <[log in to unmask]>
Reply To:
Stable Isotope Geochemistry <[log in to unmask]>
Date:
Mon, 9 Oct 2006 20:12:47 -0700
Content-Type:
text/plain
Parts/Attachments:
text/plain (28 lines)
Greetings:

  We are calibrating our new TC/EA for measuring d18O of solid  
samples. Having measured VSMOW and SLAP waters, we have calculated  
the  "source stretching" factor Y worked out by Coplen (1988) to  
normalize the d18O isotope data to the VSMOW and SLAP scales.   
Coplen, (1988) also worked out the systematics for a variety of other  
samples (e.g., sulphates, organic material, etc.) based upon a CO2- 
H2O fractionation factor, of value 1.0412. Having not done my  
homework, I assume this CO2-H2O fractionation factor is not  
applicable to CO-H2O reactions on the TC/EA? Is there a CO-H2O  
fractionation factor applicable here? References?

Help and guidance is appreciated!

Cheers,
Dyke

**************************************
Dyke Andreasen
University of California - Santa Cruz
Earth and Planetary Sciences
1156 High Street, C512
Santa Cruz, CA  95064
(831)-459-5857
[log in to unmask]
**************************************

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