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Stable Isotope Geochemistry

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Re: residual chlorine - a problem?
Arndt Schimmelmann <[log in to unmask]>
Fri, 2 Nov 2007 08:22:01 -0400
text/plain (66 lines)
Chartrand et al. (2007) reported increased D/H standard deviation due to 
a cumulative load of chlorine from GC-TC-IRMS of 71 samples of 
1,2-dichloroethane:
Rapid Communications in Mass Spectrometry, vol. 21, pages 1841-1847.

Hagit Affek wrote:
> Following up on Devon's question: do people have problems running 
> similar samples, containing halogenated organics, for compound 
> specific Hydrogen isotopes?
>
> thanks,
> hagit.
>
>
>
> Bolotin, Jakov wrote:
>> Hi Devon,
>>  
>> Not really. We have to reoxidise the reactor from time to time.
>>  
>> Regards
>>  
>> Jakov
>>
>> ------------------------------------------------------------------------
>> *From:* Stable Isotope Geochemistry [mailto:[log in to unmask]] 
>> *On Behalf Of *Devon Rowe
>> *Sent:* Mittwoch, 31. Oktober 2007 06:16
>> *To:* [log in to unmask]
>> *Subject:* [ISOGEOCHEM] residual chlorine - a problem?
>>
>> To any of you who run samples (e.g., industrial ground waters) with 
>> appreciable concentrations of chlorinated ethenes for carbon (via 
>> GC-C-IRMS), have you seen any negative effects (short term/long term) 
>> due to chlorines entering into your mass spec?
>>  
>>
>> Devon
>>
>> ------------------------------------------------------------------------
>> This message contains information that may be confidential, 
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>> intended for the exclusive use of the Addressee(s). Unless you are 
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-- 
Arndt Schimmelmann, Ph.D.
Senior Scientist
Indiana University
Department of Geological Sciences
Biogeochemical Laboratories
1001 East 10th Street
Bloomington, IN 47405-1405
Ph   (812) 855-7645
home (812) 339-3708
FAX  (812) 855-7961
e-mail:   [log in to unmask]
personal home page:   http://www.indiana.edu/~geosci/people/faculty2.php?n=schimmelmann
home page of Biogeochemical Laboratories:
http://www.indiana.edu/~geosci/research/biogeochem/

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