Fri, 2 Nov 2007 08:22:01 -0400
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Chartrand et al. (2007) reported increased D/H standard deviation due to
a cumulative load of chlorine from GC-TC-IRMS of 71 samples of
1,2-dichloroethane:
Rapid Communications in Mass Spectrometry, vol. 21, pages 1841-1847.
Hagit Affek wrote:
> Following up on Devon's question: do people have problems running
> similar samples, containing halogenated organics, for compound
> specific Hydrogen isotopes?
>
> thanks,
> hagit.
>
>
>
> Bolotin, Jakov wrote:
>> Hi Devon,
>>
>> Not really. We have to reoxidise the reactor from time to time.
>>
>> Regards
>>
>> Jakov
>>
>> ------------------------------------------------------------------------
>> *From:* Stable Isotope Geochemistry [mailto:[log in to unmask]]
>> *On Behalf Of *Devon Rowe
>> *Sent:* Mittwoch, 31. Oktober 2007 06:16
>> *To:* [log in to unmask]
>> *Subject:* [ISOGEOCHEM] residual chlorine - a problem?
>>
>> To any of you who run samples (e.g., industrial ground waters) with
>> appreciable concentrations of chlorinated ethenes for carbon (via
>> GC-C-IRMS), have you seen any negative effects (short term/long term)
>> due to chlorines entering into your mass spec?
>>
>>
>> Devon
>>
>> ------------------------------------------------------------------------
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--
Arndt Schimmelmann, Ph.D.
Senior Scientist
Indiana University
Department of Geological Sciences
Biogeochemical Laboratories
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Bloomington, IN 47405-1405
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