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Stable Isotope Geochemistry

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Stable Isotope Geochemistry <[log in to unmask]>
Subject:
Re: D2O equilibration
From:
Gilles St-Jean <[log in to unmask]>
Date:
Wed, 30 May 2001 09:49:34 -0400
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Stable Isotope Geochemistry <[log in to unmask]>
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Paul
I prepared a 2L internal standard about 10 years ago calculating D2O and
local deionized water (-84permil) to get +15permil.  I let it sit for a week
mixing regularly.  I got 15.6permil and I am still using it today.

Gilles

-----Message d'origine-----
De : Paul Brooks [mailto:[log in to unmask]]
Envoyé : 29 mai, 2001 13:53
À : [log in to unmask]
Objet : Re: [ISOGEOCHEM] D2O equilibration


Does anyone if D2O added to H2O will equilibrate to HDO, or is there no
atom exchange among water molecules?  We want to make some D enriched water
at about +500 delta units H/D, but cannot find a reference to say wether D
and H exchange on the water molecule or not.

Thanks in advance,

Paul Brooks.



Paul D. Brooks,
Dept. ESPM-ES,
147 Higard Hall MC 3110,
UC Berkeley, Ca. 94720-3110.

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phone (510)643-1748,
FAX (510)643-5098.

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