Dear Delia,
For hydrogen isotope mineral-water fractionations other than Suzuoki &
Epstein (1976) look into:
C.M. Graham and S.M.F. Sheppard, Experimental hydrogen isotope studies,
II. Fractionations in the system epidote - NaCl - H2O, epidote - CaCl2 -
H2O and epidote - seawater, and the hydrogen isotope composition of
natural epidotes., Earth Planet. Sci. Lett. 49, 237-251, 1980.
C.M. Graham, S.M.F. Sheppard and T.H.E. Heaton, Experimental hydrogen
isotope studies - I. Systematics of hydrogen isotope fractionation in
the system epidote - H2O, zoisite - H2O and AlO(OH) - H2O., Geochim.
Cosmochim. Acta 44, 353-364, 1980.
C.M. Graham, R.S. Harmon and S.M.F. Sheppard, Experimental hydrogen
isotope studies: hydrogen isotope exchange between amphibole and water.,
Am. Mineral. 69, 128-138, 1984.
C.M. Graham, J.A. Viglino and R.S. Harmon, Experimental study of
hydrogen-isotope exchange between aluminous chlorite and water and of
hydrogen diffusion in chlorite., Am. Mineral. 72, 566-579, 1987.
For tourmaline hydrogen isotope systematics the following references
might be the ones you are looking for:
D. Blamart, M. Pichavant and S.M.F. Sheppard, D/H isotopic fractionation
between tourmaline and water: The experimental calibration of
tourmaline-mineral geothermometers at 50°C to 700°C., Chem. Geol. 70,
182, 1988.
D. Blamart, M. Pichavant and S.M.F. Sheppard, Détermination
expérimentale du fractionement isotopique D/H entre tourmaline et eau à
600, 500°C et 3 kbar., C. R. Acad. Sci. Paris t. 308(Série II), 39-44,
1989.
D. Blamart, M. Boutaleb, S. Sheppard, C. Marignac and A. Weisbrod, A
comparative thermobarometric (chemical and isotopic) study of a
tourmalinized pelite and its Sn-Be vein, Walmès, Morocco., Eur. J.
Mineral. 4, 355-368, 1992.
T.G. Kotzer, T.K. Kyser, R.W. King and R. Kerrich, An emperical oxygen-
and hydrogen-isotope geothermometer for quartz-tourmaline and
tourmaline-water., Geochim. Cosmochim. Acta 57, 3421-3426, 1993.
B.E. Taylor and J.F. Slack, Tourmalinites from Appalachian - Caledonian
massive sulfide deposits: Textural, chemical, and isotopic
relationships., Econ. Geol. 79, 1703-1726, 1984.
Best wishes,
Pier de Groot
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Dr. P.A. de Groot
University of the Witwatersrand
Economic Geology Research Unit
Department of Geology
Private Bag 3
2050 Johannesburg
South Africa
Tel. +27 11 7162564
Fax. +27 11 3391697
E-mail <[log in to unmask]>
Visit the combined HOME-PAGE of EGRU-Geology on the Internet:
http://www.wits.ac.za/science/geology/1stpage.htm
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