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Date: | Wed, 6 Jun 2001 10:16:24 -0700 |
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I have sent this to the list on behalf of Gregory G. Dolnikowski as he was
unable to do so at the moment.
Thanks to everyone who answered my earlier question. It does appear that
there is no problem in mixing D2O with H2O and getting a mix of HDO. Paul.
>From: "Gregory Dolnikowski" <[log in to unmask]>
>To: <[log in to unmask]>
>Subject: HDO exchange
>Date: Tue, 29 May 2001 14:57:02 -0400
>X-Mailer: Microsoft Outlook Express 5.00.2919.6600
>
>Paul Brooks,
>
>Yes, D2O and H2O do indeed exchange deuterium to form HDO. Here are two
>citations:
>
>Studies of the Binary Reactions of H3O+(H2O)0,1,2 Ions and their Deuterated
>Analogs with D2O, H2O, and NH3
>SMITH D, ADAMS NG, HENCHMAN MJ
>JOURNAL OF CHEMICAL PHYSICS
>72 (9): 4951-4957 1980
>
>Deuterium exchange in the systems of H2O+/H2O and H3O+/H2O
>Anicich VG, Sen AD
>INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
>172 (1-2): 1-14 JAN 1998
>
>Gregory G. Dolnikowski
>
Paul D. Brooks,
Dept. ESPM-ES,
147 Higard Hall MC 3110,
UC Berkeley, Ca. 94720-3110.
[log in to unmask]
phone (510)643-1748,
FAX (510)643-5098.
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