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Stable Isotope Geochemistry

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from pp.dundee.ac.uk (pp.dundee.ac.uk [134.36.2.60]) by elk.uvm.edu (8.7.3/8.7.3) with ESMTP id DAA38654 for <[log in to unmask]>; Wed, 27 Mar 1996 03:35:43 -0500 from anatphys.dundee.ac.uk by pp.dundee.ac.uk with SMTP (PP); Wed, 27 Mar 1996 08:34:21 +0000 from ANATPHYS/MERCURYQ by anatphys.dundee.ac.uk (Mercury 1.20); 27 Mar 96 08:38:18 BST from MERCURYQ by ANATPHYS (Mercury 1.20); 27 Mar 96 08:37:47 BST
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WMAUGENSTEIN <[log in to unmask]>
Date:
Wed, 27 Mar 1996 08:37:39 GMT
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Re: deuterium in acidic water
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Dear All,

On the occasion of Natalies's problem with the Zn reduction of her 
water samples I would like to ask if someone has given any thought 
(or a shot even) to reduce water samples using Mn?

Given the fact that its redox potential (-1.18 V) is smaller than 
that of Zn (-0.7628 V) in acidic solutions it would appear to be the 
more obvious candidate. What's more, is doesn't develop an "oxid-skin" 
that renders its surface more or less inert.

I always wanted to try this one since I observed that Mn is capable 
to reduce NO3- down to NH4+ in an aqueous suspension.

Any thoughts and/or comments?

Cheers,
                 Wolfram


*****************************
Dr. W. Meier-Augenstein
Hon. Lecturer in Chemistry

University of Dundee
Dept. of Anatomy & Physiology
Small's Wynd
DUNDEE  DD1 4HN
Great Britain

Tel.: +44-(0)1382-34/5124, /4968
      +44-(0)468 -314563
Fax:  +44-(0)1382-34/5514

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