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Stable Isotope Geochemistry

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Subject:
Re: unusual slope of calibration of standards
From:
Paul Eby <[log in to unmask]>
Reply To:
Stable Isotope Geochemistry <[log in to unmask]>
Date:
Tue, 12 May 2009 11:53:36 -0700
Content-Type:
text/plain
Parts/Attachments:
text/plain (46 lines)
H3 calibration has been performed, and is consistently around 6 (not 
0.6 as I wrote below!)

Paul

At 11:17 AM 12/05/2009, you wrote:
>HI Paul--
>
>H3+ calibration???
>
>take care
>
>gerry
>
>Paul Eby wrote:
>>Listmembers,
>>
>>Has anyone ever seen a calibration slope (known and measured values 
>>of two standards) deviate significantly from the expected 0.95 to 
>>1.05? We are consistently seeing 0.67.
>>
>>This is a new Delta Advantage. d13C and d18O on a pair of OzTech 
>>CO2 standards by dual inlet both have a slope of approximately 1, 
>>so the instrument is otherwise working fine (similar results by GasBench).
>>
>>Hydrogen is a different story: a pair of OzTech standards by dual 
>>inlet has a consistent slope of 0.67, and SMOW/GISP/SLAP by 
>>H/Device shows similar results. H3 is consistently around 0.6, and 
>>the calibration performed on the H/Device seems stable enough that 
>>I could probably ignore the issue and run.
>>
>>Any suggestions out there on how this could be?
>>
>>Paul Eby
>>
>>
>>[log in to unmask]
>>Alberta Research Council
>>
>>Vancouver Island Technology Park
>>3 - 4476 Markham St.
>>Victoria, BC, Canada V8Z 7X8
>>
>>Phone: 250-483-3290
>>Fax:     250-483-1989

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