0100,0100,0100Hi William:
You can make life much easier if you first make 2 mirror-immage
slabs, one is processed as the other you keep for microsampling
under binocular microscope. In the thin section, you check the
preservation of fibrous structure of crystals under polarizing
microscope and the luminescence that they exhibit under
luminoscope as well.
You might recognize, under CL, alternate dull (summer) and
bright (winter) layers due to changes in growth rate during seasons
which is relative to the rate of incorporation of Mn that mainly
causes bright red luminescence. The bright CL may also reflect
alteration due to incorporation of Mn during diagenesis.
Therefore, you may take a fraction from each layer and check it
out under SEM to see the ultra structure and this is the most
powerfull tool that will help you indentify the altered parts because
you can see clearly the damage in the crystal structure caused by
dissolution.
In a later stage, you may run major and trace element analysis to
confirm your results from petrographic criteria and to reveal any
hiden alteration you could not recognize.
The following references will help you a lot.
Barbin, V. and Gaspard, D., 1995, Cathodoluminescence of recent
articulate brachiopod shells: Implications for growth stages and
diagenesis evaluation: Geobios, M.S., v. 18, p. 39-45.
Azmy, K.; Veizer, J.; Bassett, M. and Copper, P., 1998. OXYGEN
AND CARBON ISOTOPIC COMPOSITION OF SILURIAN
BRACHIOPODS: IMPLICATIONS FOR COEVAL SEAWATER
AND GLACIATIONS. GSA Bull., 110: 1499-1512.
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Karem Azmy, PhD.
Research Associate
Department of Earth Sciences
University of Ottawa
365 Nicholas St., Box 450, Stn. A
Ottawa, Ontario, K1N 6N5, Canada
Tel. (613) 562 5773
Fax. (613) 562 5192
e-mail [log in to unmask], [log in to unmask]
http://www.science.uottawa.ca/users/azmy/
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