Dear M. Bertal, I just had a look at your website, and it seems you have quite an assortment of products we need on a regular basis. I would appreciate it if you could send me a pricelist of the most common products for EA-IRMS (solids, liquids). Prices of cups, spare parts, etc...would be very welcome. Best regards, Peter. --- Peter Vervloedt University of Ghent Faculty of Agricultural and Applied Biological Sciences Department of Applied Analytical and Physical Chemistry Coupure 653 9000 Gent BELGIUM tel.: +32 9 264 6000 fax.: +32 9 264 6230 --- -----Oorspronkelijk bericht----- Van: Laurent BERTAL <[log in to unmask]> Aan: [log in to unmask] <[log in to unmask]> Datum: vrijdag 26 januari 2001 10:35 Onderwerp: Re: [ISOGEOCHEM] 13C analysis on samples with high S-content >Dear M Vervloedt, >You can trap Sulfur using Silver woll we can provide. We have manufacture >one special wool in silver foil, much more efficient and easy to operate >than those made of silver wire. >You also have possibility to use Silver capsules (we acn also provide)to >introduce your sample. In that case you will trap Sulphur directly in >combustion. Be carrefull you will not have flash combustion, but you will >have more oxygen available. So you have to check if carbone combustion is >complete. >Please let me know, how do you feel your combustion tube in your analyser? >If you need some samples of silver wool or capsules for trials, just let me >know > > >Sincères salutations/ Best regards > >Laurent Bertal >Gérant/Manager >Courtage Analyses Services >85 Chemin de Clères >76130 Mt St Aignan >tel + 33 2 35 07 60 00 / Fax +33 2 35 70 64 39 >e-mail : [log in to unmask] >http://www.onlinecas.com/ > > -----Original Message----- >From: Stable Isotope Geochemistry [mailto:[log in to unmask]] On >Behalf Of Peter Vervloedt >Sent: Wednesday, January 24, 2001 2:42 PM >To: [log in to unmask] >Subject: 13C analysis on samples with high S-content > >Dear Listmembers, > >I need some help on the following: > >We extracted soils with K2SO4 (0,125M, 50mL), and then freeze dried those >samples in tin cups. It was the first time we used this technique and didn't >realise the danger. > >Apparantly the very high sulfur-content in the cups causes serious >contamination of the GC (we use Anca-SL), when measuring the samples for >13C. > >Are there any of you that have experienced the same problem? Is there a way >to modify the equipment (to scrub out the sulfur), or is there another way >to get rid of the sulfur? > >Thanks a lot in advance! > >Best regards, > >Peter > >--- >Peter Vervloedt >Laboratory Of Applied Physical Chemistry >Ghent University >Coupure 653 >9000 Gent > >tel.: +32 9 264 6000 > +32 9 264 6048 >fax.: +32 9 264 6230 >--- >-----Oorspronkelijk bericht----- >Van: Stable Isotope Geochemistry <[log in to unmask]> >Aan: [log in to unmask] <[log in to unmask]> >Datum: vrijdag 20 oktober 2000 9:06 >Onderwerp: Re: [ISOGEOCHEM] Isotopic >carbonatealterationduetothermaltreatment? > > >Micha, > >depending on the water content and the presence of metastable carbonate >phases in the core there may be transformation of the carbonate fraction >into >more stable phases. Depending on a number of boundary conditions O isotope >exchange may occur. This will probably be not a serious problem for C >isotopes. During roasting some OM will decompose and create CO2. > >Regards, Michael > >Micha Horacek wrote: > >> Dear isogeochemists, >> >> I think I have to formulate my request more precisely: >> >> The palmag cores are demagnetised by heating to temperatures above 350° C >> for at least two hours (but I do not think much longer) and "roasted" at >> maximum temperature of 500° for twenty minutes. >> The cores consist of massive rock, not powder. The cores are from impure >> carbonate rocks with low organic contents. >> Can the demagnetisation process possibly change the isotope ratios, for >> example if the carbonate content of the sample is rather small? >> >> Cheers, >> Micha