Hi Dachun, What is your head-space sample / reservoir volume and how much do you withdraw? What exactly do you mean by saying "continuously sampled"? Several sub-samplings, i.e. multiple withdrawals of head-space aliquots? If so, what's the volume of such a sub-sample? Cheers, Wolfram > -----Original Message----- > From: Stable Isotope Geochemistry > [mailto:[log in to unmask]] On Behalf Of Dachun Zhang > Sent: 21 October 2004 19:51 > To: [log in to unmask] > Subject: dissolved CO2 > > > Hi, > > How much differences are the d18O of head space CO2 and the > CO2 dissolved in water (40 oC)? I found d18O is inreasingly > heavier when the CO2 is continusly sampled out from the head > space and measuered for isotopic composition. > > Regards. > > Dachun Zhang > Zymax >