Why don't you buy some high grade CO without a known isotopic composition and then calibrate it against known standards such as carbonate? For our measurements, we run two different isotopic standards with each batch of samples and don't bother to calibrate the reference gas. Anthony --- You wrote: Dear all, I'm having very big problems in finding suppliers of CO with d18O and d13C determined, in small cylinders (1L) to use in dual inlet systems. Some of the suppliers cannot send over-ocean (OzTech in USA nor from Mexico). Others apparently don't have the gas anymore in catalogue (Messer Grisheim, in Italy at least: Messer Germany did not yet reply me). So: anyone could help me? Thank you!! ---------------------------------- Giovanni Calderone, PhD EC-Joint Research Centre Institute for Health & Consumer Protection Physical and Chemical Exposure Unit - BEVABS TP740 via Fermi, 2 21020 ISPRA Italy Tel. Off.: +(39) 0332 78 5668 Tel. Lab.: +(39) 0332 78 5258 Fax: +(39) 0332 78 9303 http://ihcp.jrc.it/ http://hosting.jrc.cec.eu.int/pce/ e-mail: [log in to unmask] --- end of quote ---