Hello everyone, Our lab has been asked to analyze the hydrogen/deuterium ratio of a water sample from a crater lake. We have tried 3 times (zinc reduction method) but the results differ from each other by at least 10 per mil. The problem is that the water is very acidic (pH 1 or 2) and we can't raise the pH without adding an external source of hydrogen (hydroxide). Does anyone have an idea as to how we could obtain the hydrogen/deuterium ratio of this sample? Thanks very much Natalie Morisset