Torsten, A variation on Bill Patterson's suggestion is to introduce a small amount of saturated HgCl2 into each vessel which you are going to collect your samples in advance and then allowing them to dry completely. This way you get the Hg and no worry of spilling any crystals. Of course, if Hg is some kind of problem... Sterilization by UV? Hope life is treating you and yours well in Tuebingen. Jim >Dear Isogeochemists > >We are interested in analyzing DIC from groundwaters by acidification with >H3PO4. The water samples are commonly poisoned with HgCl2 for this method. >Would anyone know if there is an alternative to the HgCl2? > >Thanks in advance, greetings > >Torsten. > >------------------------------------ >Torsten W. Vennemann >Institute for Geochemistry >University of Tuebingen >Wilhelmstr. 56 >72074 Tuebingen >Germany > >Tel: (0)7071 29 74992 >Fax: (0)7071 29 6870 >---------------------------------- Jim Burdett Cornell Laboratory for Stable Isotope Analysis 125 Boyce Thompson Intitute Tower Rd. Ithaca NY 14853 Telephone: (607) 254-6732 (office), 254-1227 (prep lab), 254-1382 (mass specs) FAX: (607) 254-1382