Dear friends, I regularly receive samples of water in vacuum-sealed pyrex tubes furnace-combusted with zinc shots for D/H analysis. As I am not only doing such type of measurement, I often cannot perform analyses immediately. So I'd like to know whether these samples can be conserved for a while or not. May someone of you provide me with references on the subject? I personnaly cannot imagine hydrogen gas to diffuse through an amorphous glass wall. But I was told by colleagues of me that D (preferentially to H) could do bonds with SiO2 and thus induce fractionation. Thanks for advices and help. Pat __________________________________________________________ Patrick DAUBY Universite de Liège Laboratoire d'Océanologie Unité de Recherche en Biogéochimie des Isotopes Stables (URBIS) B6 Sart Tilman B-4000 Liège, Belgium Phone: +32.4.3663322 - 3663307 Fax: +32.4.3663325 Beep: 0454.700.671 (inside Benelux only) WWW: http://www.ulg.ac.be/oceanbio/urbis.htm __________________________________________________________