Hello Dachun and all isotope geochemists, In his study "Atmospheric nitrogen is a reliable standard for natural 15-N abundance measurements" (1983, Nature, vol. 303, pp. 685-687), Mariotti had found that atmospheric nitrogen is isotopically identical all over France, within the precision of his measurements. Given the good mixing of atmospheric air masses, that should be true for all locations. Is it possible that you sampled air that was isotpically shifted by the proximity of a liquid nitrogen storage tank? Nitrogen that vents from liquid nitrogen can be expected to isotopically differ from mean atmospheric nitrogen. Best wishes, Arndt ******************** Arndt Schimmelmann Biogeochemical Laboratories Indiana University Department of Geological Sciences 1005 East Tenth Street Bloomington, IN 47405-1403 U.S.A. ph 812-855-7645 fax 812-855-7961 ********************