Howdy All- In the interest of creating my everyday working carbonate standard, I've ground hand samples from a local limestone to a fine powder . I guess geomorphologists would call the resulting texture rock flour. I figured the finer the grind, the easier it would be to achieve homogeneity. It has since been pointed out to me that too fine a grind might lead to a poor standard (we haven't had a chance to start analyzing it yet). Friedman and O'Neil (1977) make mention on page KK5 that the Solenhofen LS (NBS-20) is "too fine grained to be a good and lasting standard." Does this have to do with potential contamination of atmospheric vapor, difficulties in handling the standard, or other factors? Can anyone suggest a suitable "grain size?" If my lab RH is about 17%, and I store the standard in a dessicator, do I even need to worry (excessively) about potential atmospheric vapor? Thanks in advance for any insights. Best Regards- Mark """""""""""""""""""""""""""""""""""" R. Mark Larson Research Scientist UWYO Stable Isotope Facility Dept. of Renewable Resources University of Wyoming Laramie, WY 82071-3354 Email: [log in to unmask] Phone: 307.766.5203 Fax: 307.766.6403