OK!!! I will be home early as I have finished the stuff I wanted to do !!! DATA sent to Sheffield! Hopefully that will make them happy! Andreas Pier de Groot wrote: > Moritz and Eddy, > > The value I actually gave was the value as given in one of my book chapters > on standards by Manfred Groening, referring to the Boehlke et al. (2003) > paper. I looked again in the Boehkle et al (2003) paper, and indeed, a > number of values is given. > I am not certain why Manfred selected this particular value (can you react > yourself on this, Manfred?), but I guess since Boehlke and coworkers took > into consideration the 'capital delta'17O signature (quoted is the work by > Greg Michailski and coworkers: Michailski et al. (2002) Anal. Chem., 74: > 4989-4993) of IAEA-NO-3 (= IAEA-N3) in their determination of the d18O > value, it was considered the most reliable determination of the d18O for > that reason! > It also must be notified that there is a clear difference between 'off-line' > (CO2, O2) and 'on-line' (CO) methods of roughly 2 - 3 per mil., whatever the > reason. Worrying enough.... > > In any case, we really need to have consensus about the values of standards > and reference materials. Having a list of values for the same standard or > reference material is not serving anybody. > If the given d18O value is the best one (I followed Manfred Groening in > this) might raise dispute by some. But we have to decide which value we do > accept! We need to have an isotopic value solidly calibrated and traceable > to the N-isotope scale - that should be the choice. Otherwise we cannot > compare with each other and may bias our interpretations. > > Pier. > > > >>Eddy, >> >>The Boehlke paper is indeed the latest report on d18O of IAEA-N3. But be >>aware that there are quite a number of other (lower) values reported (in >>parts compiled in the Boehlke paper). >> >>Moritz >> >> >>On Tuesday, December 9, 2003, at 05:16 AM, eminet wrote: >> >> >>>Dear list members, >>>Has anyone of you a d18O value for the reference IAEA-NO-3 (for which >>>d15N=4.7)? >>>Thanks, >>>Eddy >>> >>>Eddy Minet >>>Centre for the Environment >>>Trinity College Dublin >>>Dublin 2 (Ireland) >>>e-mail: [log in to unmask] >>>tel: +353(0)1 608 2403 >>>mobile: +353(0)86 827 4921 >>> >>> >> >>Moritz F. Lehmann >>Department of Geosciences >>Princeton University >>Guyot Hall >>Princeton, NJ 08544 >>phone: (609) 258-7544 >>fax: (609) 258-0796 e-mail: [log in to unmask] >> >> > -- Dr. Andreas Heinemeyer E- mail: [log in to unmask] University of York (CTCD-York) Dept. of Biology (& SEI) Mail Area 2 'Below Ground Ecology' York, YO10 5DD, UK Phone: 0044-1904-32-8553 (Biol.) or: ...-43-2896 (SEI) Fax : 0044-1904-43-2860 (Biol.) or: ...-43-2898 (SEI) WEB: http://www-users.york.ac.uk/~ah126/AH_web.html